Product ID:POLY BD R-45M RESIN
MSDS Date:01/26/1993
FSC:8040
NIIN:00N060202
MSDS Number: BXSSQ

ELF ATOCHEM

2000 MARKET ST
PHILADELPHIA, PA 19103
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 215-582-1551

Cage: IO927

ELF ATOCHEM NORTH AMERICA INC

PHILADELPHIA, PA 19103-3222 US

Telephone: 800-245-5858

Cage: 86460

HYDROXY TERMINATED 1,3-BUTADIENE HOMOPOLYMER

CAS: 69102-90-5

Fraction By Weight: 99.9%

OSHA PEL N/K

ACGIH TLV: N/K

<500 PPM

CAS: 100-40-3

RTECS: GW6650000

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: 0.1 PPM, A2

< 5PPM

CAS: 106-99-0

RTECS: EI9275000

Fraction By Weight: <0.1%

OSHA PEL 1000 PPM

ACGIH TLV: 2 PPM; A2

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

OVARIAN EFTS IS DEMONSTRATED BY THEIR ABILITY TO

RTECS: 9999999ZZ

METABOLITE, VCH-1,2-EPOXIDE. NO EFTS WERE SEEN ON

RTECS: 9999999ZZ

VCH ORALLY. REDUCTIONS IN BODY WEIGHTS & NUMBERS OF

RTECS: 9999999ZZ

CHANGES IN STANDARD TESTS USING BACTERIAL CELLS.

RTECS: 9999999ZZ

W/HEATING, THERE IS POTENTIAL FOR RELEASE OF

RTECS: 9999999ZZ

TO DRAW DUSTS AND FUMES FROM WORKER BREATHING ZONES.

RTECS: 9999999ZZ

"INDUSTRIAL VENTILATION,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: DIRECT CONT/VAPS MAY
CAUSE SLIGHT IRRIT. SKIN: LIQ MAY CAUSE SLIGHT IRRIT. CHRONIC: NONE
KNOWN. IN RUSSIAN WORKERS EXPOS TO HIGH VCH CONCS (271-677PPM), EYE
& NOSE IRRIT, HDCH, SOME WHITE BLOOD CELL REDUCTIONS & IMPAIRED
CARBOHYDRATE METABOLISM WERE REPORTED. RPTD ADMIN OF VCH TO RATS &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MICE BY INHAL (4-MONTHS) WAS REPORTED
TO PRODUCE SOME WHITE BLOOD CELL REDUCTIONS & TO AFFECT BLOOD
CIRCULATION, WHILE RPTD ORAL DOSING (3-MONTHS) OF RATS & MICE
PRODUCED KIDNEY TOX IN MALE RATS & OVARIAN EFTS IN FEMALE MICE AT
DOSE THAT PRODUCED MANY ANIMAL DEATHS. NTP CONDUCTED LONG-TERM
(2-YR) (SUP DAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:EYES: IMMED FLUSH W/FLOWING WATER FOR AT LEAST 15 MIN. SEE MD
IF IRRIT PERSISTS. SKIN: REMOVE CONTAM CLTHG & WASH EXPOS SKIN
W/LGE AMTS OF WATER. SEE MD IF IRRIT PERSISTS. INGEST: NO HARMFUL
EFTS ANTI CIPATED IF SWALLOWED. SEE MD IF IRRIT PERSISTS. INHAL: NO
HARMFUL EFTS ANTICIPATED FROM BRTHG LOW CONC OF VAPS. IF PROBLEM
DEVELOPS, REMOVE PERS TO FRESH AIR & SYPPLY OXYGEN IF NEC.

Flash Point Method:OC
Flash Point:>400F,>204C
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MOVE CONTR FROM FIRE AREA IF POSS. COOL
FIRE-EXPOS CONTRS W/WATER WELL AFTER FIRE IS OUT TO PREVENT POSS
EXPLO. HEAT FROM FIRE CAN GENERATE FLAM VAP HVR/AIR.

Spill Release Procedures:VENTILATE AREA AND REMOVE ALL IGNITION
SOURCES. CONTAIN SPILL BY BUILDING A DIKE USING ABSORBENT MATERIAL.
COLLECT REMAINDER OF SPILL WITH ABSORBENT MATERIAL AND PLACE
MATERIAL INTO A DRUM APPROVED FO R WASTE DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MIN VAP BY SEALING IN TIGHTLY CLSD
CONTR. STORE IN COOL, DRY, WELL-VENT AREA. KEEP AWAY FROM HEAT,
SPARKS, OPEN FLAMES, & STRONG OXIDIZING AGENTS.
Other Precautions:PROT FROM FREEZING. IF FROZEN, THAW & MIX THORO
BEFORE USE. AVOID OVERHEATING. AVOID SKIN & EYE CONT. THIS PROD
CONTAINS TRACE AMTS OF ODOROUS MATL IDENTIFIED AS
4-VINYLCYCLOHEXENE (VCH). UNDER AGGRES SIVE CNDTNS OF PHYSICAL
HNDLG OR (ING 8)

Respiratory Protection:FOR CNDTNS WHERE EXPOS TO DUST & FUMES IS
APPARENT, A NIOSH/MSHA APPRVD RESP FOR DUSTS, MISTS & FUMES APPROP
TO AIRBORNE CONC MAY BE WORN. WHERE VAPS GENERATED, A NIOSH/MSHA
APPRVD ORG RESP SUITABLE T O AIRBORNE CONCS IS RECOMMENDED.
Ventilation:PROVIDE LOC EXHAUST VENT WHERE HEAT CAN CAUSE POLYMER
BREAKDOWN, E.G. EXTRUSION, MOLDING & WHERE THERE IS NEED (ING 9)
Protective Gloves:NITRILE (NBR) OR NATURAL RUBBER.
Eye Protection:ANSI APPRVD CHEM WORK GOG W/SIDESHIELDS.
Other Protective Equipment:WEAR IMPERVIOUS BODY COVERING AND BOOTS
WHERE SPILLS OR SPLASHING OCCUR.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: STUDIES ON EFTS OF ORAL ADMIN OF VCH TO MALE & FEMALE
RATS & MICE. DEATHS WERE SO NUMEROUS AMONG MALE & FEMALE RATS &
MALE MICE THAT NTP CONSIDERED THESE STUDIES INADEQ TO JUDGE CARCI N
OF VCH. INCR IN OVARIAN TUMORS WAS OBSERVED IN FEMALE MICE. INCR
SENSITIVITY OF MOUSE AS MODEL FOR VCH INDUCED (ING 4)

Boiling Pt:B.P. Text:>572F,>300C
Spec Gravity:0.90
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH MILD HYDROCARBON ODOR

Stability Indicator/Materials to Avoid:YES
ACIDS AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, OPEN FLAME, PROLONGED STORAGE AT
ELEVATED TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF CARBON AND BUTADIENE.

Waste Disposal Methods:DISP OF SOLID WASTE AT PROPERLY PERMITTED
LANDFILLS OBSERVING ALL LOC, STATE, & FED REGS. CONTAM LIQS SHOULD
BE CONCENTRATED & INCIN AT PROPERLY PERMITTED DISP SITE AGAIN
OBSERVING ALL LOC, STATE, & F ED REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.